Boosting the Reactivity of Gallium: Philipp Dabringhaus and Krossing Group report a procedure to highly active Ga(I) cations coordinated by bisphosphines. The cations allow for the activation of H–B and H–Si, and CC multiple bonds. Now out in Nature Synthesis!
tinyurl.com/galliumkrossing
Proud that my first paper as corresponding author together with Krossing Group has just been published! 🎉
nature.com/articles/s4416…
Activation of the GaI Cation for Bond Activation: from Oxidative Additions into C-Cl and H-P Bonds to Reversible Insertion into P4 (I. Krossing et al.) Philipp Dabringhaus, Krossing Group onlinelibrary.wiley.com/doi/10.1002/ch…
We are very happy to share a new chapter for our low-valent Ga chemistry! Check out insitu generated, reactive (di-)gallenes just published in Nature Synthesis by first author Philipp Dabringhaus!
nature.com/articles/s4416…
Low-Valent MxAl3 Cluster Salts with Tetrahedral [SiAl3]+ and Trigonal-Bipyramidal [M2Al3]2+ Cores (MSi/Ge) (Krossing) Krossing Group David Scheschkewitz Philipp Dabringhaus #openaccess thanks to #projektDEAL onlinelibrary.wiley.com/doi/10.1002/an…
![Low-Valent MxAl3 Cluster Salts with Tetrahedral [SiAl3]+ and Trigonal-Bipyramidal [M2Al3]2+ Cores (MSi/Ge) (Krossing) @KrossingGroup @scheschkewitz @PDabringhaus #openaccess thanks to #projektDEAL onlinelibrary.wiley.com/doi/10.1002/an…](https://pbs.twimg.com/media/FmWZ15bXgAAsY9k.png "Angewandte Chemie (@angew_chem) on Twitter photo 2023-01-13 11:47:00 Low-Valent MxAl3 Cluster Salts with Tetrahedral [SiAl3]+ and Trigonal-Bipyramidal [M2Al3]2+ Cores (MSi/Ge) (Krossing) @KrossingGroup @scheschkewitz @PDabringhaus #openaccess thanks to #projektDEAL onlinelibrary.wiley.com/doi/10.1002/an…")
Now online:
Article by Philipp Dabringhaus Krossing Group Universität Freiburg and co-workers
In situ formation of reactive (di)gallenes for bond activation
nature.com/articles/s4416… ($)
Marcel Bamberg Krossing Group Thanks Marcel! To you, too! Looking forward hearing all about it at GAIN later this year.
Check out this 🔥 article from Krossing Group and first author Philipp Dabringhaus:
'Cationic dialanes with fluxional π-bridged cyclopentadienyl ligands'
rsc.li/3hG8cHv
Universität Freiburg Krossing Group Philipp Dabringhaus Nature Chemistry livMatS Wunderschön.😍 Glückwünsche! 👏
angew_chem: Low-Valent MxAl3 Cluster Salts with Tetrahedral [SiAl3]+ and Trigonal-Bipyramidal [M2Al3]2+ Cores (MSi/Ge) (Krossing) Krossing Group David Scheschkewitz Philipp Dabringhaus #openaccess thanks to #projektDEAL bit.ly/3ix8mBI bit.ly/3Xx2w21